Fabrication of Embedded Silver Nanowires on Arbitrary Substrates with Enhanced Stability via Chemisorbed Alkanethiolate
<Abstract>
We propose a versatile yet practical transferring technique to fabricate a high
performance and extremely stable silver nanowire (AgNW) transparent electrode
on arbitrary substrates. Hydroxylated poly(ethylene glycol) terephthalate (PET)
or poly(dimethylsiloxane) (PDMS) deposited with AgNWs was selectively decorated
to lower its polar surface energy, so that the AgNWs were easily and efficiently
transferred into an epoxy resin (EPR) as a freestanding film (AgNWs–EPR) or onto
various substrates. The AgNWs–EPR capped with alkanethiolate monolayers
exhibits high conductivity, low roughness, ultraflexibility, and strong corrosion
resistance. Using the transferring process, AgNWs–EPR was successfully constructed
on rough, adhesive, flimsy, or complex curved substrates, including PET, thin optically
clear adhesive, papers, a beaker, convex spherical PDMS, and leaves. A flexible touch
panel enabling multitouch and a curved transparent heater on a beaker were first
fabricated by using the composite film. These demonstrations suggest that the proposed
technique for AgNWs is a promising strategy toward the next generation of flexible
/portable/wearable electronics.